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2 article(s) from Walker, Amy V

Electron-induced deposition using Fe(CO)₄MA and Fe(CO)₅ – effect of MA ligand and process conditions

Hannah Boeckers,
Atul Chaudhary,
Petra Martinović,
Amy V. Walker,
Lisa McElwee-White and
Petra Swiderek

Beilstein J. Nanotechnol. 2024, 15, 500–516, doi:10.3762/bjnano.15.45

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Figure 1: Molecular structures of (left) tetracarbonyliron(η²-methyl acrylate) (Fe(CO)₄MA) and (right) iron p...

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Figure 2: (a) ESD of neutral species during irradiation with 50 eV electrons from an Fe(CO)₄MA multilayer on ...

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Figure 3: Time evolution of characteristic ESD signals recorded during irradiation with 50 eV electrons of an...

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Figure 4: TDS obtained (a) from a pristine Fe(CO)₄MA multilayer without electron irradiation (denoted as 0 µC...

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Figure 5: (a) AES recorded with an electron energy of 5 keV on a freshly sputtered Ta substrate (bottom). AES...

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Figure 6: AES intensities for Ta_NNN (green), C_KLL (yellow), O_KLL (blue), and Fe_LMM (red) measured as peak-to-...

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Figure 7: AES intensities for Ta_NNN (green), C_KLL (yellow), O_KLL (blue), and Fe_LMM (red) measured as peak-to-...

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Figure 8: AES intensities for Ta_NNN (green), C_KLL (yellow), O_KLL (blue), and Fe_LMM (red) measured as peak-to-...

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Figure 9: Free Gibbs energy for thermal loss of the MA ligand (top) and the CO ligand (bottom) from Fe(CO)₄MA...

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Published 08 May 2024

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Application of visible-light photosensitization to form alkyl-radical-derived thin films on gold

Rashanique D. Quarels,
Xianglin Zhai,
Neepa Kuruppu,
Jenny K. Hedlund,
Ashley A. Ellsworth,
Amy V. Walker,
Jayne C. Garno and
Justin R. Ragains

Beilstein J. Nanotechnol. 2017, 8, 1863–1877, doi:10.3762/bjnano.8.187

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Scheme 1: Proposed visible-light-promoted thin film deposition on Au surface.

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Scheme 2: Phthalimide esters used for the deposition of thin films.

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Figure 1: Nanopores within a film of Au–Me on Au(111) produced using immersion particle lithography and the r...

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Figure 2: Attempted nanoshaving of the Au–Me Film on Au (111). (a) Topography image of nanopores within the f...

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Figure 3: Au–Me thin film prepared in the absence of Ru(bpy)₃Cl₂ was not robust. (a) Topography image of nano...

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Figure 4: Film of Au–NHBoc prepared on Au(111) with nanopores using particle lithography. (a) Topograph of na...

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Figure 5: Au–NHBoc film after storage in ambient conditions for six months. (a) Topography image; (b) zoom-in...

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Figure 6: IRRAS Spectrum of Au–Me.

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Figure 7: IRRAS Spectrum of Au–NHBoc.

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Figure 8: Au 4f, C 1s and O 1s photoelectron spectra of the deposited Au–Me layer.

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Figure 9: a) Positive ion mass spectrum m/z 40–75 and b) negative ion mass spectrum m/z 190–290 of the deposi...

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Scheme 3: A mechanistic hypothesis for multilayer formation, crosslinking, and alkene formation.

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Full Research Paper

Published 06 Sep 2017

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Electron-induced deposition using Fe(CO)4MA and Fe(CO)5 – effect of MA ligand and process conditions

Application of visible-light photosensitization to form alkyl-radical-derived thin films on gold

Electron-induced deposition using Fe(CO)₄MA and Fe(CO)₅ – effect of MA ligand and process conditions